Direct Radical Polymerization of 4‐Styryldiphenylphosphine: Preparation of Cross‐Linked and Non‐Cross‐Linked Triphenylphosphine‐Containing Polystyrene Polymers.

Abstract

Carboxylic acid estersCarboxylic acid esters Q 0530 Direct Radical Polymerization of 4-Styryldiphenylphosphine: Preparation of Cross-Linked and Non-Cross-Linked Triphenylphosphine-Containing Polystyrene Polymers. -A facile route to the phosphine (III) is reported. It smoothly undergoes copolymerization with styrene in the presence and absence of a cross-linker. The resulting phosphine-containing polymers are able to promote Mitsunobu reaction as well as bromination of alcohols. -(CHOI, M. K. W.; HE, H. S.; TOY*, P. H.; J. Org.