Abstract:The pyridine derivative, 4-(dimethylamino)pyridine (DMAP), is important in a surprisingly wide variety of applications spanning chemical, biological and technological domains. Empirically, the protonation state of DMAP and how this protonation state is changed with adsorption on a solid surface, is known to play a crucial role in many of these applications. However, the direct spectroscopic evidence for bias dependent DMAP (de)protonation at solid/aqueous interfaces is still very limited. Here, we employed sur… Show more
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