Direct Observation of Enhanced Iodine Binding within a Series of Functionalized Metal–Organic Frameworks with Exceptional Irradiation Stability
Jiangnan Li,
Xinran Zhang,
Mengtian Fan
et al.
Abstract:Optimization of active sites and stability under irradiation are important targets for sorbent materials that might be used for iodine (I 2 ) storage. Herein, we report the direct observation of I 2 binding in a series of Cu(II)-based isostructural metal−organic frameworks, MFM-170, MFM-172, MFM-174, NJU-Bai20, and NJU-Bai21, incorporating various functional groups (−H, −CH 3 , − NH 2 , −C�C−, and −CONH−, respectively). MFM-170 shows a reversible uptake of 3.37 g g −1 and a high packing density of 4.41 g cm −3… Show more
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