Direct observation of cobalt precipitates in nanocrystalline Cu–Co powder synthesised by laser ablation

The orderings of atoms in bimetallic 1.6–2.1 nm-large CuCo nanoparticles, important as catalytic and magnetic materials, were studied using a combination of DFT calculations with a topological approach. The structure and magnetism of Cu50Co151, Cu101Co100, Cu151Co50, and Cu303Co102 nanoparticles; their resistance to disintegrating into separate Cu and Co species; as well as the exposed surface sites, were quantified and analyzed, showing a clear preference for Cu atoms to occupy surface positions while the Co atoms tended to form a compact cluster in the interior of the nanoparticles. The surface segregation of Co atoms that are encapsulated by less-active Cu atoms, induced by the adsorption of CO molecules, was already enabled at a low coverage of adsorbed CO, providing the energy required to displace the entire compact Co species inside the Cu matrices due to a notable adsorption preference of CO for the Co sites over the Cu ones. The calculated adsorption energies and vibrational frequencies of adsorbed CO should be helpful indicators for experimentally monitoring the nature of the surface sites of CuCo nanoparticles, especially in the case of active Co surface sites emerging in the presence of CO.

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Direct observation of cobalt precipitates in nanocrystalline Cu–Co powder synthesised by laser ablation

Cited by 3 publications

References 22 publications

Electromagnetic wave absorption properties of carbon-encapsulated Co–Cu alloy nanoparticles prepared by gas explosion

Electromagnetic wave absorption properties of carbon-encapsulated Co–Cu alloy nanoparticles prepared by gas explosion

EM Wave Absorption Properties of Carbon-Encapsulated Co-Cu Alloy Nanoparticles Prepared by Gas Explosion

Chemical Orderings in CuCo Nanoparticles: Topological Modeling Using DFT Calculations

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