Direct measurement of the inverse secondary isotope effects of Rh(I)-C2H4 and Rh(I)-C2H3D utilizing gas chromatography

The article reviews the use of isotopes to determine mechanisms of homogeneously catalyzed reactions. Kinetic isotope effects (KIEs) and equilibrium isotope effects (EIEs) on single steps as well as those on complete catalytic cycles are considered. Coverage includes EIEs and KIEs for the addition and elimination of H 2 and hydrocarbons to metal complexes. Isotope effects for proton, hydrogen atom, and hydride transfer to and from metal complexes, along with insertions into metal–hydrogen bonds, are discussed in detail. Isotope effects on olefin polymerization, oxidation, hydrogenation, and hydroformylation are discussed. Isotope effects on spectroscopic properties are included by way of discussion and interpretation.

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Isotope Methods – Homogeneous

Bullock

Bender

2002

Encyclopedia of Catalysis

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Direct measurement of the inverse secondary isotope effects of Rh(I)-C2H4 and Rh(I)-C2H3D utilizing gas chromatography

Cited by 1 publication

References 33 publications

Isotope Methods – Homogeneous

Isotope Methods – Homogeneous

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