Direct GC determination of methylmercury chloride on HBr-methanol-treated capillary columns

Mizuishi, Kazuko; Takeuchi, Masahiro; Hobo, Toshiyuki

doi:10.1007/bf02466315

Cited by 13 publications

(10 citation statements)

References 22 publications

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“…6 To verify this hypothesis, samples containing 25 mL volumes of a 40 ng mL 21 TBTCl solution and 1 g of NaCl were placed in an amber glass vial and capped with a PTFE-silicone septum.…”

Section: Volatilization Of Tbtcl Aqueous Solutionsmentioning

confidence: 99%

See 1 more Smart Citation

Gas phase detection of tributyltin chloride arising from aqueous and solid matrices

Bancon-Montigny¹,

Maxwell²,

Yang³

et al. 2002

J. Anal. At. Spectrom.

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Access and use of this website and the material on it are subject to the Terms and Conditions set forth at Gas phase detection of tributyltin chloride arising from aqueous and solid matrices Bancon-Montigny, C.; Maxwell, P.; Yang, L.; Mester, Z.; Sturgeon, R.; Lam, J.http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=fr L'accès à ce site Web et l'utilisation de son contenu sont assujettis aux conditions présentées dans le site LISEZ CES CONDITIONS ATTENTIVEMENT AVANT D'UTILISER CE SITE WEB. NRC Publications Record / Notice d'Archives des publications de CNRC:http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?action=rtdoc&an=8900361&lang=en http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?action=rtdoc&an=8900361&lang=fr READ THESE TERMS AND CONDITIONS CAREFULLY BEFORE USING THIS WEBSITE.http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=en Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n'arrivez pas à les repérer, communiquez avec nous à PublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. Questions? Contact the NRC Publications Archive team atPublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. If you wish to email the authors directly, please see the first page of the publication for their contact information. NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. For the publisher's version, please access the DOI link below./ Pour consulter la version de l'éditeur, utilisez le lien DOI ci-dessous.http://doi.org/10.1039/b207944eJournal of Analytical Atomic Spectrometry, 17, 11, pp. 1506Spectrometry, 17, 11, pp. -1510Spectrometry, 17, 11, pp. , 2002 Gas phase detection of tributyltin chloride arising from aqueous and solid matrices{ The vapour phase above water spiked with tributyltin chloride (TBTCl) and PACS-2 sediment certified reference material was sampled with a solid phase microextraction fiber. The collected volatile compounds were analysed by GC-MS using a HBr-methanol-treated capillary column. Two ion sources were used for this study and their performance characteristics compared. These were electron impact (EI) and negative chemical ionisation (NCI), which allowed both detection of trace amounts of analytes (NCI source) and their identification. This approach provides structural information on the sampled species; at this stage no quantitation was attempted. TBTCl can be detected in the vapour phase above saline water or PACS 2 sediment after one night of passive sampling without any stirring or heating of the sample. This work indicates the need to consider evaporation of TBT as the chloride as a mechanism of loss...

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“…6 To verify this hypothesis, samples containing 25 mL volumes of a 40 ng mL 21 TBTCl solution and 1 g of NaCl were placed in an amber glass vial and capped with a PTFE-silicone septum.…”

Section: Volatilization Of Tbtcl Aqueous Solutionsmentioning

confidence: 99%

“…Fig. 3 Effect of extraction time on chromatographic peak area response above aqueous solutions containing 40 ng mL 21 of TBTCl. Fig.…”

Section: Solid Samplesmentioning

confidence: 99%

Gas phase detection of tributyltin chloride arising from aqueous and solid matrices

Bancon-Montigny¹,

Maxwell²,

Yang³

et al. 2002

J. Anal. At. Spectrom.

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“…The addition of KBr was found to lead to an increase of the retention times and peak intensity in HPLC (Schickling and Broekaert, 1995). Also in GC, the derivatization of methyl mercury by reaction with HBr (Mizuishi et al, 1997) or Kl (Kato et al, 1992;Barshick et al, 1999;Lansens et al, 1990) is well established prior to chromatography of mercury compounds on polar columns. The bromides formed were further stabilized by adding HBr to the carrier gas.…”

Section: Derivatization Using Halogenationmentioning

confidence: 99%

Analytical Methods for Speciation of Mercury in Gas Condensates: Critical Assessment and Recommendations

Bouyssière

Baco

Savary

et al. 2000

Oil & Gas Science and Technology - Rev. IFP

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Résumé -Méthodes analytiques pour la spéciation du mercure dans les condensats de gaz : évaluation critique et conseils -La présence de multiples formes du mercure dans les condensats de gaz peut poser de graves problèmes de corrosion d'installations ou d'empoisonnement de catalyseurs. Afin de comprendre et d'optimiser le procédé de démercurisation, il est nécessaire de connaître la concentration des différentes espèces présentes. Cet article de synthèse sur les méthodes analytiques de spéciation du mercure dans les condensats de gaz présente les avantages et les inconvénients de ces méthodes. Une attention particulière est donnée à la chromatographie en phase gazeuse couplée à une détection spécifique, présentée ici comme la meilleure technique pour l'analyse du mercure en spéciation dans des échantillons organiques. Cet article abordera les problèmes liés à la justesse des données disponibles, à la stabilité des composés du mercure dans les solutions organiques, ainsi qu'à la formation possible d'artefacts et à l'inexistence de matériel de référence.Mots-clés : mercure, condensats de gaz, spéciation, chromatographie en phase gazeuse. Abstract -Analytical Methods for Speciation of Mercury in Gas Condensates

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“…5 Figure 6 shows the chromatograms of methylmercury chloride separated by the capillary column which was treated with methanolic HBr. 70 The authors 71 also used NICI-MS as a highly selective and sensitive method for organotin halides. Using the doping technique and GC-NICI-MS, were studied the direct and sensitive determination of traces of TBT and TPhT halides.…”

Section: ·4 Direct Analysis Of Organotin Halidesmentioning

confidence: 99%

Determination of Organotin Compounds in Environmental Samples

2000

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Due to the impact of organotin compounds in the environment, a necessity exists for a rapid, sensitive and accurate analytical method to determine the levels of the compounds in the different environmental components. A variety of analytical techniques has been developed for the speciation of organotin compounds. Most of them are based on gas chromatography (GC) connected with atomic absorption spectrometry (AAS), flame photometry (FPD), mass spectrometry (MS), inductively coupled plasma (ICP) or microwave-induced plasma atomic emision spectrometry (MIP-AES). Since GC requires volatility of analytes, their derivatization into volatile species is usually indispensable. Direct GC of organotin halides without derivatization, however, could offer a highly selective and sensitive analytical technique for the trace determination at the level of less than ng l -1 in aquatic samples. As an alternative approach, high performance liquid chromatography, has become a popular technique. It mainly uses AAS, ICP-MS and fluorometry for the eluate detection. ICP-MS has been applied practically because of its inherent selectivity and sensitivity.

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Direct GC determination of methylmercury chloride on HBr-methanol-treated capillary columns

Cited by 13 publications

References 22 publications

Gas phase detection of tributyltin chloride arising from aqueous and solid matrices

Gas phase detection of tributyltin chloride arising from aqueous and solid matrices

Analytical Methods for Speciation of Mercury in Gas Condensates: Critical Assessment and Recommendations

Determination of Organotin Compounds in Environmental Samples

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