Abstract:The interaction between ethene and Cl2 on
ZnO(0001̅)
has been investigated using X-ray photoelectron spectroscopy (XPS),
temperature-programmed desorption (TPD), and density functional theory
(DFT) calculations. At 110 K, the Cl2 molecule is perpendicularly
adsorbed on ZnO(0001̅). Upon heating, Cl2 is dissociated
on the surface in the temperature range of 200–230 K. When
the surface coadsorbed with Cl2 and ethene is heated, the
desorption of 1,2-dichloroethane is observed at ∼230 K. The
desorption temperature … Show more
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