Direct Aroylation of Olefins through a Cobalt/Photoredox‐Catalyzed Decarboxylative and Dehydrogenative Coupling with α‐Oxo Acids

Davies, Alex M.; Hernandez, Rafael D.; Tunge, Jon A.

doi:10.1002/chem.202203641

Cited by 6 publications

(2 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…7 However, poor stereoselectivity ( E /Z ratio) was always obtained using this strategy when alkene substrates with two similar substitutions were used (Scheme 1b). 8 Therefore, the development of efficient approaches to solve this problem is of great importance and highly desirable.…”

Section: Introductionmentioning

confidence: 99%

Highly regioselective C–H carbonylation of alkenes with phenyl formateviaaryl to vinyl 1,4-palladium migration

et al. 2023

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Highly regioselective C–H carbonylation of alkenes with phenyl formateviaaryl to vinyl 1,4-palladium migration

et al. 2023

View full text Add to dashboard Cite

show abstract

“…The recent development of radical acylation–functionalization of alkenes provides a practical pathway for producing β-functionalized ketones. − We assume that CBZ6* generated from the irradiation of CBZ6 with visible light could reduce benzoyl chloride to a radical anion. The acyl radical is then generated, releasing the chloride anion.…”

mentioning

confidence: 99%

Photocatalytic Redox-Neutral Alkoxyacylation of Alkenes

Cen,

Sun,

et al. 2023

Org. Lett.

View full text Add to dashboard Cite

Recent Developments on Photochemical Synthesis of 1,n‐Dicarbonyls

Mondal

Chatterjee²,

Maity

2023

Chemistry A European J

View full text Add to dashboard Cite

Review doi.org/10.1002/chem.202301147 1,n-dicarbonyls are one of the most fascinating chemical feedstocks finding abundant usage in the field of pharmaceuticals. Besides, they are utilized in a plethora of synthesis in general synthetic organic chemistry. A number of 'conventional' methods are available for their synthesis, such as the Stetter reaction, Baker-Venkatraman rearrangement, oxidation of vicinal diols, and oxidation of deoxybenzoins, synonymous with unfriendly reagents and conditions. In the last 15 years or so, photocatalysis has taken the world of synthetic organic chemistry by a remarkable renaissance. It is fair to say now that everybody loves the light and photoredox chemistry has opened a new gateway to organic chemists towards milder, more simpler alternatives to the previously available methods, allowing access to many sensitive reactions and products. In this review, we present the readers with the photochemical synthesis of a variety of 1,n-dicarbonyls. Diverse photocatalytic pathways to these fascinating molecules have been discussed, placing special emphasis on the mechanisms, giving the reader an opportunity to find all these significant developments in one place.

show abstract

Direct Aroylation of Olefins through a Cobalt/Photoredox‐Catalyzed Decarboxylative and Dehydrogenative Coupling with α‐Oxo Acids

Cited by 6 publications

References 0 publications

Highly regioselective C–H carbonylation of alkenes with phenyl formateviaaryl to vinyl 1,4-palladium migration

Highly regioselective C–H carbonylation of alkenes with phenyl formateviaaryl to vinyl 1,4-palladium migration

Photocatalytic Redox-Neutral Alkoxyacylation of Alkenes

Recent Developments on Photochemical Synthesis of 1,n‐Dicarbonyls

Contact Info

Product

Resources

About