Direct Alkylative Amination Using 1‐Allylsilatrane**

Abstract

Homoallylic amines prepared via addition of allylsilanes often require preformed imine substrates, metal catalysts, fluoride activators, or use of protected amines. In this metal‐free, air‐ and water‐tolerant procedure, aromatic aldehyde and aniline substrates undergo direct alkylative amination using easily accessible 1‐allylsilatrane.