Abstract:Aliphatic alkylamines are abundant feedstock and versatile building blocks for many organic transformations. While remarkable progress has been made to construct C−N bonds on aliphatic and aromatic carbon centers, the activation and functionalization of C(sp 3 )−NH 2 bonds in primary alkylamines remain a challenging process. In the present work, we discovered an unprecedented method to directly activate the C(sp 3 )−NH 2 bond of primary alkylamines by a high-valent dinuclear Co III,IV 2 (μ-O) 2 diamond core co… Show more
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