Direct access to carbamates via acylation of arylamines with dialkyl azodicarboxylates under metal-free conditions
Liangxin Fan,
Mengyang He,
Xinyuan Liu
et al.
Abstract:A novel C–N coupling of arylamines with dialkyl azodicarboxylates under metal-free conditions for the rapid assembly of carbamates has been achieved. The synthetic application of products was exemplified by several intriguing chemical operations.
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