Diphosphinoazine rhodium(III) and iridium(III) octahedral complexes

Pošta, Martin; Čermák, Jan; Vojtı́šek, Pavel; Sýkora, Ján; Cı́sařová, Ivana

doi:10.1016/j.ica.2008.03.080

Cited by 6 publications

(2 citation statements)

References 28 publications

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“…On the basis of calculations, the reaction is believed to avoid direct oxidative addition of N-N bond to rhodium. We believe that in our case the oxidation of metal is caused by the presence of chloroform, similarly to the oxidation of Rh(I) observed in cycloocta-1,5-diene complexes [23], azine moiety being at the same time cleaved into two didentate phosphine-imine ligands. The source of hydrogen for iminato to imine transformation is unclear.…”

supporting

confidence: 68%

Square planar diphosphinoazine rhodium(I) amido carbonyl complexes with an unsymmetrical PNP′ pincer-type coordination

Pošta

Čermák

Sýkora

et al. 2008

Journal of Organometallic Chemistry

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supporting

confidence: 68%

Square planar diphosphinoazine rhodium(I) amido carbonyl complexes with an unsymmetrical PNP′ pincer-type coordination

Pošta

Čermák

Sýkora

et al. 2008

Journal of Organometallic Chemistry

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“…Rhodium(III) and iridium(III) octahedral complexes of general formula [MCl 3 {R 2 PCH 2 C(t-Bu)@NN@C(t-Bu)CH 2 PR 2 }] (M = Rh, Ir; R = Ph, c-C6H11, i-Pr, t-Bu;) were prepared (Scheme 23) [66].…”

Section: Group Ixb -Co Rh Irmentioning

confidence: 99%

Polydentate phosphines

Pascariu¹,

Iliescu²,

Popa³

et al. 2009

Journal of Organometallic Chemistry

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a b s t r a c tPhosphines are one of the most important classes of ligands in chemistry, in both the industrial and academic spheres. This review deals with the design and properties of polydentate phosphines, an original and broad class of multidentate ligands. The multidentate nature of these species has led to special properties, in which the spatial proximity of phosphorus atoms is crucial. The first part gives an overview of oligodentates polyphosphines in which is discussed the types and the basic routes for their synthesis. The review continues with the most important synthetic routes for obtaining complexes. Because of huge amount of literature data this review is not exhaustive, but it collects the most relevant findings in this area. The restriction to structural and spectroscopic properties allows us for a well organized handling of the complex material.

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