Morphology
regulation is an effective strategy for improving the
sensor sensitivity of transition metal oxide nanostructures. In this
work, SnO2 with three different morphologies (nanorods,
nanoparticles, and nanopillars) has been synthesized by a simple one-step
solvothermal process with the addition of various solute ratios at
180 °C for 6 h for detecting formaldehyde (HCHO) at the optimum
working temperature of 320 °C. Compared to nanorods and nanopillars,
the created SnO2 nanoparticles exhibit a much faster response
time and sensitivity than other samples, showing the fastest recovery
time (18 s) with the highest sensitivity of 6–100 ppm of the
HCHO gas. The sensing mechanism of the sensors is investigated by
Brunauer–Emmett–Teller (BET) methods and X-ray photoelectron
spectroscopy (XPS) analysis, revealing that the pore size distribution
and amount of OV and OC improve the charge transfer
and HCHO adsorption of nanoparticle sensors. Such an effect of morphology
control on sensing performance paves an idea for the development of
different structure-based HCHO sensors.