“…Potassium diethyldithiocarbamate was prepared as reported previously. 52 Briefly, a mixture of KOH (2 g…”
Section: Synthesis Of Precursors (1-5)mentioning
confidence: 99%
“…Potassium diethyldithiocarbamate was prepared as reported previously. 52 Briefly, a mixture of KOH (2 g, 35.6 mmol) in ethanol (50 mL) was stirred in a three neck flask for 20 minutes. Diethylamine (3.68 mL, 35.6 mmol) was added to this solution and stirred for 30 minutes.…”
Pyrite(FeS2) and transition metal doped pyrite, MxFe1−xS2 (where M = Co, Ni, Cu and Zn), have been deposited on various substrates using aerosol-assisted chemical vapour deposition (AACVD).
“…Potassium diethyldithiocarbamate was prepared as reported previously. 52 Briefly, a mixture of KOH (2 g…”
Section: Synthesis Of Precursors (1-5)mentioning
confidence: 99%
“…Potassium diethyldithiocarbamate was prepared as reported previously. 52 Briefly, a mixture of KOH (2 g, 35.6 mmol) in ethanol (50 mL) was stirred in a three neck flask for 20 minutes. Diethylamine (3.68 mL, 35.6 mmol) was added to this solution and stirred for 30 minutes.…”
Pyrite(FeS2) and transition metal doped pyrite, MxFe1−xS2 (where M = Co, Ni, Cu and Zn), have been deposited on various substrates using aerosol-assisted chemical vapour deposition (AACVD).
“…Zimmerman et al 19 provide data which agree (from the inductive .point of view) that the limiting resonance structure B possesses the stronger ligand field. Their conclusions19 are based on correlations between spectroscopic parameters and changes in the ligand field strength of the dtc ligand as measured by the pXa of H2NRR,+.…”
Section: Introductionmentioning
confidence: 88%
“…The spectrometer, calibration procedures, and the treatment of the data have been described previously. 19 The Mossbauer data of this paper are from room-temperature measurements of the Fe(NO)(dtc)2 compounds in the solid state. The isomer shifts (IS) and quadrupole splittings (A£q) are accurate to ±0.01 mm/s.…”
“…Thus Fe(III) SSPs actually convert to formation of Fe(II) species in the decomposition media. Since thiuram disuldes are oxidising agents, adding to low valent metal centres as two dithiocarbamate ligands via an oxidativeaddition process, [67][68][69][70][71][72] we considered that an equilibrium was operating. Hu and Zhang previously considered the role of thiuram disuldes in the solvothermal synthesis of CdS 73 and we have also recently shown that addition of tetra-isobutylthiuram disulde (3) to the oleylamine solutions of [Ni(S 2 CN i Bu 2 ) 2 ] can have a signicant effect on the nanomaterials generated.…”
Section: (V) Decomposition Of [Fe(s 2 Cnr 2 ) 3 ] With Added Thiuram mentioning
Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.
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