(Diorganodithiocarbamato)iron complexes. Effect of organic substituents

Synthesis of pyrite thin films and transition metal doped pyrite thin films by aerosol-assisted chemical vapour deposition

“…Potassium diethyldithiocarbamate was prepared as reported previously. 52 Briefly, a mixture of KOH (2 g…”

“…Potassium diethyldithiocarbamate was prepared as reported previously. 52 Briefly, a mixture of KOH (2 g, 35.6 mmol) in ethanol (50 mL) was stirred in a three neck flask for 20 minutes. Diethylamine (3.68 mL, 35.6 mmol) was added to this solution and stirred for 30 minutes.…”

Nitrosylbis(diorganodithiocarbamato)iron complexes. Effect of organic substituents

“…Zimmerman et al 19 provide data which agree (from the inductive .point of view) that the limiting resonance structure B possesses the stronger ligand field. Their conclusions19 are based on correlations between spectroscopic parameters and changes in the ligand field strength of the dtc ligand as measured by the pXa of H2NRR,+.…”

“…The spectrometer, calibration procedures, and the treatment of the data have been described previously. 19 The Mossbauer data of this paper are from room-temperature measurements of the Fe(NO)(dtc)2 compounds in the solid state. The isomer shifts (IS) and quadrupole splittings (A£q) are accurate to ±0.01 mm/s.…”

Fe(ii) and Fe(iii) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

“…Thus Fe(III) SSPs actually convert to formation of Fe(II) species in the decomposition media. Since thiuram disuldes are oxidising agents, adding to low valent metal centres as two dithiocarbamate ligands via an oxidativeaddition process, [67][68][69][70][71][72] we considered that an equilibrium was operating. Hu and Zhang previously considered the role of thiuram disuldes in the solvothermal synthesis of CdS 73 and we have also recently shown that addition of tetra-isobutylthiuram disulde (3) to the oleylamine solutions of [Ni(S 2 CN i Bu 2 ) 2 ] can have a signicant effect on the nanomaterials generated.…”