1991
DOI: 10.1063/1.460504
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Diode laser spectroscopy of the four radicals, CdD, ZnD, BaD, and SrD, in their 2∑ ground state

Abstract: The infrared spectra of several isotopic forms of the monodeuterides of the metals cadmium, zinc, barium, and strontium have been measured in their ground electronic state (2∑) in the gas phase using a diode laser spectrometer. The analysis of the experimental data was carried out in two ways: (a) a complete set of Dunham parameters was determined for each isotopic species independently and (b) all the available data over both deuterated and protonated species of a particular compound were simultaneously fitte… Show more

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Cited by 19 publications
(23 citation statements)
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“…The number of rotational lines in each band was limited, due to spectral gaps in the diodes available. For example, only one rotational line was observed in the P-branch of the v = 2 ‹ 1 bands of ZnD and CdD [44,45]. We included all the diode laser infrared lines in our data set, and there was no systematic discrepancy between those lines and our calibrated line positions.…”
Section: Discussionmentioning
confidence: 94%
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“…The number of rotational lines in each band was limited, due to spectral gaps in the diodes available. For example, only one rotational line was observed in the P-branch of the v = 2 ‹ 1 bands of ZnD and CdD [44,45]. We included all the diode laser infrared lines in our data set, and there was no systematic discrepancy between those lines and our calibrated line positions.…”
Section: Discussionmentioning
confidence: 94%
“…The published diode laser infrared spectra of ZnH, ZnD, CdH, and CdD contained the v = 1 ‹ 0 and v = 2 ‹ 1 bands for these species [44,45]. The number of rotational lines in each band was limited, due to spectral gaps in the diodes available.…”
Section: Discussionmentioning
confidence: 99%
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“…We do not reproduce those expressions here; B* e , * e , and k 1 are also given in Eqs. [16]- [18] of Ref. (12), respectively.…”
Section: Dunham Treatmentmentioning
confidence: 98%