Abstract:Here we show that a tridentate bis(aryloxide)anilide‐ligated titanium/potassium scaffold promotes functionalization of coordinated N2 with CO2 and CS2 through formation of N−C bonds. Treatment of a naphthalene complex with N2 gave an end‐on bridging dinitrogen complex featuring a [Ti2K2N2] core. The dinitrogen complex underwent insertion of CO2 into each Ti−NN bond to afford an N,N′‐dicarboxylated hydrazido complex. Stepwise nitrogen‐carbon bond formation at coordinated N2 proceeded to afford an unsymmetric hy… Show more
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