Dinitrogen Binding and Activation: Bonding Analyses of Stable V(III/I)–N2–V(III/I) Complexes by the EDA–NOCV Method from the Perspective of Vanadium Nitrogenase
Abstract:The FeVco cofactor of nitrogenase (VFe
7
S
8
(CO
3
)C) is an alternative in the molybdenum (Mo)-deficient
free soil living azotobacter vinelandii. The rate of N
2
reduction to NH
3
by FeVco is a few times higher than
that by FeMoco (MoFe
7
S
9
C) at low temperature.
It provides a N source in the form of ammonium ions to the soil. This
biochemical NH
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“…The knowledge of organometallic complexes activating nitrogen would help in this effort. [167][168][169][170] These results indicate that multimetallic compounds 168,171 are necessary to reduce and/or activate N 2 . In addition, the site for CO 2 reduction should be near.…”
Section: Advances In Direct Urea Synthesismentioning
Making chemicals from the air is a visionary objective that can potentially revolutionise chemical production. This critical review shows that the basic elements to realise this dream exists, although many...
“…The knowledge of organometallic complexes activating nitrogen would help in this effort. [167][168][169][170] These results indicate that multimetallic compounds 168,171 are necessary to reduce and/or activate N 2 . In addition, the site for CO 2 reduction should be near.…”
Section: Advances In Direct Urea Synthesismentioning
Making chemicals from the air is a visionary objective that can potentially revolutionise chemical production. This critical review shows that the basic elements to realise this dream exists, although many...
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