Dinitramide and its salts

Synthesis and Structures of Triorganochalcogenium (Te, Se, S) Dinitramides

“…The dinitramide anion was first discovered by Russian chemists in 1971, [1] but was kept secret until it was independently rediscovered in the late 1980s in the USA. [2] Afterwards, the Russian work was summarized in a series of publications, [1,[3][4][5][6][7][8][9][10] new aspects were added by different groups, [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25] and also theoretical aspects of the dinitramide anion have been reported. [26][27][28] An overview of structural trends and variations in dinitramide salts has been given, [10,29,30] and potential applications for various dinitramide salts have been discussed.…”

Toward the Synthesis of Tetrazino‐­tetrazine 1,3,6,8‐Tetraoxide (TTTO): An Approach to Non‐annulated 1,2,3,4‐Tetrazine 1,3‐Dioxides

“…Notably, methylation of N ‐nitroamines gave a mixture of O ‐ and N ‐methylated products 29. At the same time, isopropylation of silver salts of N ‐nitroamines in Et 2 O as solvent yielded predominantly O ‐substituted products 12,30…”

Kinetics Analysis of the Initial Decomposition Reaction of Ammonium Dinitramide

“…By Yu-ichiro IZATO, 1) Hiroto HABU 2) and Atsumi MIYAKE The condensed phase decomposition reactions of ADN were investigated both experimentally and theoretically. Thermogravimetric-differential thermal analysis coupled with mass spectrometry (TG-DTA-MS) was employed to generate Friedman plots for the thermal decomposition of ADN with the evolution of N2O and N2.…”

“…1, and was first synthesized in 1971 at the Zelinsky Institute of Organic Chemistry in the former Soviet Union. [1][2][3] In 1989, ADN was independently produced at the Stanford Research Institute. 4,5) Over the past four decades, significant research has been conducted to gain an understanding of the combustion wave structure and burning rate characteristics of ADN.…”