Dimethyl(methylthio)sulfonium Tetrafluoroborate (DMTSF)

Adams, Edward J.

doi:10.1002/047084289x.rd349

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Electrophilic Sulfenofunctionalization Of Alkenes1

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Cited by 4 publications

(1 citation statement)

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“…Therefore, various hetero-nucleophiles, such as amines, azide, acetate, phosphines, fluoride, have been employed in the sulfenofunctionalization of alkenes. 46…”

Section: Electrophilic Sulfenofunctionalization Of Alkenesmentioning

confidence: 99%

Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation

2023

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“…Therefore, various hetero-nucleophiles, such as amines, azide, acetate, phosphines, fluoride, have been employed in the sulfenofunctionalization of alkenes. 46…”

Section: Electrophilic Sulfenofunctionalization Of Alkenesmentioning

confidence: 99%

Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation

2023

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Electrophilic Sulfenylation/Cyclization of N‐Aryl and N‐Benzyl Propynamides: Synthesis of Sulfenyl Quinolinones and 3H‐Benzo[c]azepin‐3‐ones

Yang,

Tang,

Liu

et al. 2023

Asian J Org Chem

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Quinolinones and benzo[c]azepinones are important cores in biologically active molecules. We report the cyclization of N‐substituted propynamides, initiated by readily available electrophilic sulfenylating agent, enabling the synthesis of quinolinones and benzo[c]azepinones in exceedingly simple conditions. The approach shows excellent generality to the substrates and tolerability of functional groups. The anti‐inflammatory effect of the newly synthesized 3‐sulfenyl quinolinone and the 4‐sulfenyl benzo[c]azepinone products are tested, and two compounds are confirmed to have inhibitive effect on TNF‐α expression.

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Benzazetidines and Related Compounds: Synthesis and Potential

Salvio

Placidi

Bella

2020

Chemistry A European J

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Benzazetidines are a class of N‐heterocycles potentially very interesting for a variety of purposes, including biological applications and drug design. In the past, their high ring strain has hampered the development of trustable, general, and efficient synthetic methodologies for their preparation. In this review article, the aim is to disclose all the literature contributions about the synthesis of these compounds and the study of their reactivity, from the early examples to the most recent synthetic approaches. Recently, there has been a growth of interest for this heterocycle, driven by the publication of novel synthetic methodologies based on palladium‐catalyzed intramolecular C−H amination and organocatalyzed ring‐closure of 2‐(N‐Boc‐anilino)‐α‐ketoesters/amides.

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Dimethyl(methylthio)sulfonium Tetrafluoroborate (DMTSF)

Cited by 4 publications

References 63 publications

Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation

Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation

Electrophilic Sulfenylation/Cyclization of N‐Aryl and N‐Benzyl Propynamides: Synthesis of Sulfenyl Quinolinones and 3H‐Benzo[c]azepin‐3‐ones

Benzazetidines and Related Compounds: Synthesis and Potential

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