The high Tc cuprate superconductors are noted for their anisotropic layered structure, certain of these materials indeed tend toward the limit of a Lawrence-Doniach superconductor. However, YBa2Cu3O 7−δ has a smaller anisotropy than would be expected from its interlayer spacing. This is due to the cuprate chains in the structure. To investigate the influence of the chain oxygen on transport properties critical current versus applied field angle measurements were performed on fully oxygenated and de-oxygenated YBa2Cu3O 7−δ thin films and optimally oxygenated Y0.75Ca0.2Ba2Cu3O 7−δ thin films. The films were grown on 10• mis-cut SrTiO3 substrates to enable the intrinsic vortex channelling effect to be observed. The form of the vortex channelling minimum observed in field angle dependent critical current studies on the films was seen to depend on film oxygenation. The vortex channelling effect is dependent on a angular dependent cross-over to a string-pancake flux line lattice. The results obtained appear to be consistent with the prediction of Blatter et al. [Rev. Mod. Phys., 66 (4): 1125] that increased superconducting anisotropy leads to the kinked string-pancake lattice existing over a smaller angular range. [2,3,4,5] (the large uncertainty in the Bi 2 Sr 2 Ca 1 Cu 2 O 8+x value is due to the difficulty in measuring its c axis transport properties).The structure of YBCO contains 'cuprate chains' inside the blocking layers between the cuprate planes associated with superconductivity. In most cuprate superconductors the blocking layers act as an insulating charge reservoir, in YBCO however, the cuprate chains also have superconducting properties [6]. This is the feature of YBCO which leads to the lower anisotropy seen in YBCO as compared to that predicted on the basis of the interlayer spacing. The chain oxygen in YBCO is highly mobile, under doping or over doping of the material by moving the oxygenation away from δ ∼ 0.08 is associated with a reduction in T c . A reduced oxygenation level will, however, also increase the superconducting anisotropy of the material by disrupting the cuprate chains. Importantly the removal of oxygen from the chains does not increase pinning [7,8]. However, there is a definite increase in superconducting anisotropy with δ at larger values [9, 10], indeed Deak et al. [11] indicate that the anisotropy more than doubles for δ > 0.2.Intrinsic vortex channelling along the a-b planes has previously been reported in optimally doped YBCO films grown on mis-cut (vicinal) substrates [12]. The development of the channelling minima in these measurements has been attributed to the appearance of a kinked (string/pancake) vortex state as the angle, θ, between the a-b planes and the applied field is reduced. The pinning of vortex string elements against a Lorentz force directed parallel to the a-b planes is relatively weak. By using a vicinal geometry thin film it is The angle θ is that between the applied magnetic field and the a-b crystallographic planes. The angle φ is that of the rotation of ...