Dimensional Crossover and Proton Conductivity in Copper-Based Coordination Polymers by Coordinative Guest Insertion
Yasaswini Oruganti,
Dongwook Kim,
Dae-Woon Lim
Abstract:Metal−organic materials (MOMs) are receiving widespread interest for use in many energy-related applications due to their tunable structure attained by the deliberate selection of metal and ligand components and their associated structure− property relationships. In this work, we demonstrate the dimensional crossover of discrete metal−organic polyhedra, CuMOP-3 (0-D, [Cu 24 (5-sip) 24 (S) 24 ]•xS; 5-sip = 5-sulfoisophthalic acid, C 8 O 7 H 5 S), into Cu-based coordination polymers, CuCP-1 (2-D, [Cu(Im) 4 •Cu 2… Show more
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