Dilute Element Compounds: A Route to Enriching Inorganic Functional Materials

Lin, Aming; Chen, Ming; Sun, Yi‐Yang

doi:10.1021/acs.jpclett.1c02490

Cited by 3 publications

(3 citation statements)

References 66 publications

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“…Inorganic functional crystal materials have been widely used in the fields of sound, light, heat, electricity, magnetism, force, etc., which have gained extensive attention from scientists. [ 1–7 ] Among them, nonlinear optical (NLO) crystals and birefringent crystals are the “chips” of optoelectronic industry, which play a crucial role in laser frequency conversion and polarized light modulation, and have been widely applied to information, industry, medical, military, and many other aspects. [ 8–15 ]…”

Section: Introductionmentioning

confidence: 99%

“…Inorganic functional crystal materials have been widely used in the fields of sound, light, heat, electricity, magnetism, force, etc., which have gained extensive attention from scientists. [1][2][3][4][5][6][7] Among them, nonlinear optical (NLO) crystals and birefringent crystals are the "chips" of optoelectronic industry, which play a crucial role in laser frequency conversion and polarized light modulation, and have been widely applied to information, industry, medical, military, and many other aspects. [8][9][10][11][12][13][14][15] Up to now, a series of NLO materials have been synthesized by traditional synthesis methods including high-temperature solid-state method, hydrothermal method, aqueous solution method, and so on.…”

Section: Introductionmentioning

confidence: 99%

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Deep Eutectic Solvents Synthesis of A₂Sb(C₂O₄)Cl₃ (A = NH₄, K, Rb) with Superior Optical Performance

Zhang

Wang

Luo

et al. 2023

Advanced Optical Materials

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Section: Introductionmentioning

confidence: 99%

“…Inorganic functional crystal materials have been widely used in the fields of sound, light, heat, electricity, magnetism, force, etc., which have gained extensive attention from scientists. [1][2][3][4][5][6][7] Among them, nonlinear optical (NLO) crystals and birefringent crystals are the "chips" of optoelectronic industry, which play a crucial role in laser frequency conversion and polarized light modulation, and have been widely applied to information, industry, medical, military, and many other aspects. [8][9][10][11][12][13][14][15] Up to now, a series of NLO materials have been synthesized by traditional synthesis methods including high-temperature solid-state method, hydrothermal method, aqueous solution method, and so on.…”

Section: Introductionmentioning

confidence: 99%

Deep Eutectic Solvents Synthesis of A₂Sb(C₂O₄)Cl₃ (A = NH₄, K, Rb) with Superior Optical Performance

Zhang

Wang

Luo

et al. 2023

Advanced Optical Materials

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“…A well-known example is Li 7 La 3 -Zr 2 O 12 , whose conductivity in the cubic structure can be two orders of magnitude higher than that in the tetragonal phase. 38,39 To induce phase change, the concept of dilute element compounds (DECs) 40 is of particular interest. DECs contain a relatively small amount of a dopant element so that the Na-richness can be preserved.…”

Section: Introductionmentioning

confidence: 99%

A hierarchical approach to designing a Na-rich phosphide solid-state electrolyte for Na-ion batteries

Lin,

Shi,

Wei

et al. 2024

J. Mater. Chem. A

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Exploring the Synthesis of Novel Sillenite Bi12SnO20: Effect of Calcination Temperature on the Phase Formation and Catalytic Performance

Baaloudj,

Kenfoud,

Brienza

et al. 2024

Catalysts

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Sillenite materials have been the focus of intense research in recent years due to their unique properties and distinct structure with the I23 space group. This electronic structure has reflected high-quality applications and results for some environmental processes such as photocatalysis. This paper investigates the synthesis of a new sillenite, Bi12SnO20, and its characteristics, emphasizing its potential for photocatalytic applications. The sillenite Bi12SnO20 has been synthesized through the co-precipitation method by mixing the appropriate ratio of Bi and Sn ions. The obtained particles after precipitation and drying were characterized by thermogravimetric analysis (TGA) and then calcined at different temperatures based on this analysis. The phase has been identified by structural analysis using X-ray diffraction (XRD), and its morphology after identification was carried out by scanning electron microscopy (SEM). The calcination temperature has been found to have a critical role in obtaining the phase, where the phase was found to be formed at temperatures between 310 and 400 °C and changed to other phases within higher temperatures. The physicochemical properties of this sillenite were also studied by Fourier-transform infrared spectroscopy (FTIR) and UV Visible Spectrometer (UV-Vis). To study the obtained phases at different calcination temperatures, performance testing was performed under visible light to remove different contaminants, which are Tetracycline, Bisphenol A, and Rhodamine B. The phase Bi12SnO20 obtained at 350 °C with a catalyst dose of 1 g/L showed the highest performance for removing these pollutants with concentrations of 20 mg/L, with an efficiency of almost 100% within 2 h. This work will be useful as an important resource and strategy for the development of this sillenite material in its pure phase.

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Dilute Element Compounds: A Route to Enriching Inorganic Functional Materials

Abstract: Computational details, classification of 182 cubic DECs, and some atomic structures of DECs discussed in the main text (PDF)

Cited by 3 publications

References 66 publications

Deep Eutectic Solvents Synthesis of A₂Sb(C₂O₄)Cl₃ (A = NH₄, K, Rb) with Superior Optical Performance

Deep Eutectic Solvents Synthesis of A₂Sb(C₂O₄)Cl₃ (A = NH₄, K, Rb) with Superior Optical Performance

A hierarchical approach to designing a Na-rich phosphide solid-state electrolyte for Na-ion batteries

Exploring the Synthesis of Novel Sillenite Bi12SnO20: Effect of Calcination Temperature on the Phase Formation and Catalytic Performance

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Dilute Element Compounds: A Route to Enriching Inorganic Functional Materials

Abstract: Computational details, classification of 182 cubic DECs, and some atomic structures of DECs discussed in the main text (PDF)

Cited by 3 publications

References 66 publications

Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance

Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance

A hierarchical approach to designing a Na-rich phosphide solid-state electrolyte for Na-ion batteries

Exploring the Synthesis of Novel Sillenite Bi12SnO20: Effect of Calcination Temperature on the Phase Formation and Catalytic Performance

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Product

Resources

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Deep Eutectic Solvents Synthesis of A₂Sb(C₂O₄)Cl₃ (A = NH₄, K, Rb) with Superior Optical Performance

Deep Eutectic Solvents Synthesis of A₂Sb(C₂O₄)Cl₃ (A = NH₄, K, Rb) with Superior Optical Performance