A family of polymers
[Ln2(ad)(Had)2(NO3)2(H2L)2(H2O)2]·2H2O (Ln = Nd (1), Sm (2), Eu (3)) and [Ln(ad)(H2L)(H2O)2]·NO3·2H2O (Ln
= Gd (4), Tb (5), Dy (6)) was
synthesized. The polymers were
characterized by powder X-ray diffraction (PXRD), infrared spectra
(IR), single-crystal X-ray diffraction, thermogravimetric analysis
(TG), and elemental analysis (C, H, N). On the basis of the luminescence
properties of the polymers, we used polymer 5 as an example
to detect thiamines (TPP, TMP, TCl). In the way that was expected,
polymer 5 could quickly detect TPP, TMP, and TCl, which
could be used as a typical luminescence sensing material in the field
of optical detection.