Diimido‐, Imido(oxo)‐, Dioxo‐ und Imido(alkyliden)‐Halbsandwich‐Verbindungen über selektive Hydrolyse und α—H‐Abstraktion an Organylkomplexen des sechswertigen Molybdäns und Wolframs

Abstract

Diimido-, Imido(oxo)-, Dioxo-und Imido(alkyliden)-Halbsandwich-Verbindungen über selektive Hydrolyse und α؊H-Abstraktion an Organylkomplexen des sechswertigen Molybdäns und Wolframs

Monomeric cyclopentadiene molybdenum oxides and their carbonyl precursors as epoxidation catalysts

“…The decomposition of Cp * MoO 2 Cl was found to be thermal, but accelerated by light and inhibited by dry oxygen. Cp * MoO 2 CH 3 could also be obtained by hydrolysis of Cp * Mo(N t Bu) 2 CH 3 with excess aqueous HCl in THF [18].…”

Mononuclear Organomolybdenum(VI) Dioxo Complexes: Synthesis, Reactivity, and Catalytic Applications

“…Cp*MoO 2 CH 3 ( 59 ) could also be obtained by hydrolysis of Cp*Mo(N t Bu) 2 CH 3 with excess aqueous HCl in THF …”

Organorhenium(vii) and organomolybdenum(vi) oxides: syntheses and application in olefin epoxidation

“…In the following years several other methods for the preparation of CpMoO 2 Cl and Cp*MoO 2 Cl appeared in the literature. [90][91][92][93][94][95] The most convenient method -to our experience -is the oxidative decarboxylation of Cp Mo(CO) 3 Cl (Cp = g 5 -(C 5 H 5 ) and derivatives) with TBHP (see eqn. ( 7)).…”