Diffusion as an Aid in the Analysis of Gaseous Paraffin Hydrocarbon Mixtures

Baxter, Robert A.; Beckham, Leland J.

doi:10.1021/ja01337a002

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Differential Rates Of Diffusion Have1

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1939

1963

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“…been applied to mixtures of gases based on an extension of the Maxwell diffusion equation (1) and on the application of Graham's law to each component of an effusing mixture (3). These methods do not involve the direct application of the chemical kinetic principles as done here.…”

Section: Differential Rates Of Diffusion Havementioning

confidence: 99%

Analysis of Mixtures Using Differential Kinetics with Separation Processes.

Siggia¹,

Hanna²,

Serencha³

1963

Anal. Chem.

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Chemical kinetic considerations are applicable to separation processes for quantitatively analyzing components in unresolvable mixtures. Distillation, diffusion, and dialysis were used. Analysis by this approach is simple and appears to be widely applicable to two-component systems.Three-component systems were successfully analyzed using dialysis.Components may be quantitatively determined in mixtures by application of chemical kinetic principles and equations to physical separation processes such as distillation, diffusion, and dialysis. In these cases, separation

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Section: Differential Rates Of Diffusion Havementioning

confidence: 99%