This paper describes the performance of Ni-P and Ni-Mo-P alloy coatings deposited by
electroless plating on the aluminum alloy 5052 to evaluate the corrosion resistance, thermal stability
and electro-conductivity of coating assemblies. Corrosion behaviors of the obtained deposits in a
0.5M H2SO4 environment were investigated. The crystalline state and morphologies of Ni-P and Ni-
Mo-P alloys were examined by field emission scanning electron microscopy (FE-SEM). The
experimental results indicate that the Ni-Mo-P coating operated at 70°C and pH 9.0 has a
nanocrystalline structure and its corrosion resistance in a 0.5M H2SO4 environment can be enhanced
by the co-deposition of Mo as compared to Ni-P films. It has also been found that the Ni-Mo-P
ternary alloys reveal good thermal stability after annealing at 400°C. Based on the excellent
performance of Ni-Mo-P ternary alloys, these alloys have a potential to be applied to precision
mould, optical parts mould, and surface metallization of substrates.