Differential pulse voltammetric determination of hexavalent chromium using nickel hexacyanoferrate modified glassy carbon electrode

Abstract

The current boom in the industrial sector of the country is arise scientific concern about environmental contamination by heavy metals such as chromium. The objective of this project is to fabricate a sensitive and selective electrode for differential pulse voltammetric determination of Cr (VI) in water samples and demonstrate its applicability in complex matrices such as tannery effluent. The drop casting method is use for electrode development. Experimental variables that can influence the DPV response of the developed electrode for Cr (VI) including strength of supporting electrolytes, pH of the solution, and concentration parameters were optimized. The figures of merit of the developed electrode were evaluated and the applicability was demonstrated through determination of Cr (VI) in tannery effluent water. The developed electrode was detected a very low level of Cr (VI) in acetate buffer at pH 5 with limit of detection and limit of quantification 0.0885 and 0.2950 μmol L −1 , respectively. The linear calibration plot is R 2 value of 0.999 suggesting a very good correlation between DPV current response and concentration of Cr (VI). The current electrode was simple to develop and can successfully be applied for the determination of Cr (VI) in wastewater samples.

Advances in Water Resource Management: An In Situ Sensor Solution for Monitoring High Concentrations of Chromium in the Electroplating Industry

“…Inductively Coupled Plasma Mass Spectrometry (ICP-MS) techniques offer high sensitivity [16]. Voltammetry techniques like Stripping Voltammetry and Differential Pulse Voltammetry (DPV) provide electrochemical insights [17,18]. X-ray Fluorescence (XRF), especially Energy-Dispersive X-ray Fluorescence (EDXRF), allows for non-destructive analysis [19].…”