Abstract:This study investigates the adsorption and oxidation of isoprene, the most abundant biogenic volatile organic compound, on two common Mn(IV) (hydr)oxides in Earth's surface environment, birnessite and cryptomelane. Both minerals show high adsorption capability toward isoprene under increasing environmental temperature and low relative humidity, whereas the adsorbed isoprene on birnessite is oxidized into carboxylate species, mainly formate. For both Mn(IV) (hydr)oxides, the adsorption of isoprene not only redu… Show more
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