The dielectric environment of thin semiconductor nanowires can affect the charge transport properties inside the wire. In this work, it is shown that Coulomb impurity scattering inside thin nanowires can be damped strongly by coating the wire with a high-κ dielectric. This will lead to an increase in the mobility of free charges inside the wire.PACS numbers: 73.50.-h Remarkable advances in crystal growth technology have recently enabled the fabrication of a variety of freestanding semiconductor nanostructures such as 0-dimensional (0D) nanocrystal quantum dots, 1D nanowires (NWs) and nanotubes, and 2D nanomembranes and graphene. Charge transport properties in such nanostructures is being intensively investigated, in the hope that they might find usage in electronic and optical devices in the future. These 'bottom-up' nanostructures differ from the more extensively studied epitaxial nanostructures created by heterostructure bandgap engineering in one crucial aspect. The dielectric environment of epitaxial nanostructures is essentially the same as the semiconducting region (dielectric constant s ) where electrons and holes reside. However, for bottom-up nanostructures, the dielectric environment ( e ) can be modified after growth. This feature offers a novel tool to engineer interactions between carriers and/or impurities by environment-mediated Coulomb interactions.The effect of the dielectric environment on charge transport properties of 'bottom-up' nanostructures has not received much attention, as compared to its effect on optical properties [1]. Recent work [2] has shown that in 2D nanomembranes the electron mobility can be increased by 1-2 orders of magnitude by coating them with a high-κ dielectric material. The purpose of this work is to investigate the effect of the dielectric environment on electron transport in semiconductor nanowires. Semiconductor NWs can now be grown with diameters of a few nanometers, which is smaller than the thermal de Broglie wavelength of the carriers, while their lengths can exceed few micrometers. At these length scales, the reduced density of states due to quantum confinement is expected to suppress scattering, and lead to high carrier mobilities [3]. Recent experiments [4] have demonstrated improved carrier mobilities in Ge/Si nanowire field-effect transistors coated with high-κ (HfO 2 ) dielectrics.In early work on carrier transport of 1D semiconductor nanowires [5,6], the effect of dielectric mismatch on transport properties was not investigated. Vagner and Mosko showed in their treatment of a 1D electron gas confined in a freestanding 2D membrane that the dielectric mismatch leads to a large decrease in mobility if the structure is freestanding [7]. In this letter, we show that FIG. 1: Calculated Coulomb potential contours due to a point charge inside a nanowire for three different dielectric environments: e = 1, 11, 100, s = 11. The potential is strongly enhanced for freestanding wires ( e = 1), whereas it is strongly damped for a high-κ coating.for 1D nanowires, the ...