Thermally stimulated luminescence ͑TSL͒ glow curves and emission spectra were studied in undoped and Ce-doped Lu 3 Al 5 O 12 single crystals by wavelength resolved TSL measurements in the 10-310 K temperature range. Isothermal phosphorescence measurements in the 10-100 K range were also performed, which point to the existence of a tunneling-driven radiative recombination process. These processes can explain the presence and time-dependence of the submicrosecond slow decay component in the scintillation decay. Electron paramagnetic resonance experiments suggest the presence of Lu Al defects in the vicinity of Ce 3+ ions, which are the most probable electron and hole traps participating in the tunneling-driven radiative recombination process.