Dielectric and spectroscopic study of binary mixture of Acrylonitrile with Chlorobenzene

Deshmukh, S. D.; Pattebahadur, K. L.; Mohod, A. G.; Undre, P. B.; Patil, S. S.; Khirade, P. W.

doi:10.1063/1.5032694

Cited by 11 publications

(2 citation statements)

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“…The reported values of ε0 and τ of the pure ACRN and 1,4-DX are in good agreement with the earlier work [10,11,15,21,22], and the values of relaxation time keep rising as the concentration of 1,4-DX in ACRN increases. Figs.…”

Section: Static Dielectric Constant (ε0 ) and Relaxation Time (τ)supporting

confidence: 91%

“…It is highly flammable and toxic by nature. The physiochemical properties and FTIR studies were applied to find out the intermolecular interactions of a binary liquid mixture of acrylonitrile with chlorobenzene and bromobenzene [10,11]. However, 1,4-dioxane (DX) [C4H8O2] is a non-hydrogen bonded liquid treated as a non-polar solvent, having a very small dipole moment and no pair formation takes place between two DX Molecules [12].…”

Section: Introductionmentioning

confidence: 99%

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Dielectric study of a binary mixture of acrylonitrile with 1,4-dioxane using a TDR

Dongre,

Gubre,

Garad

et al. 2023

Preprint

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The frequency-dependent complex permittivity spectra (CPS) of acrylonitrile (ACRN) and 1,4-dioxane (DX) binary mixture in the range from 10 MHz to 30 GHz were measured using the time domain reflectometry (TDR) technique. Experimentally obtained CPS was fitted into the Debye equation. Dielectric relaxation behaviors that depend on temperature and concentration were discussed. The obtained dielectric parameters are reported. The Kirkwood correlation and Bruggeman factor have been used to analyze the molecular association and hydrogen bonding interactions in the mixture.

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Section: Static Dielectric Constant (ε0 ) and Relaxation Time (τ)supporting

confidence: 91%