Proton relaxation rates in solutions MnCl2-CD3OH and MnCl2-C2D5OH are reported and from these data rotational correlation times for the solvation complexes are determined. Proton and deuteron relaxation rates for the hydroxyl, methylene, and methyl group in solutions of Mg(C104)2, CaCl2, NaC104, Nal, and KI in methyl alcohol and ethyl alcohol are reported, and correlation times for the various groups are determined. The various correlation times are compared with one another and, in those cases where they differ for a given solvation complex, intermolecular or intramolecular motions are postulated. The results are also compared with predictions derived from pertinent theories currently available. It is found that the description of the internal motions by the theory is not satisfactory in all cases.