Die Komplexchemie niederer Schwefeloxide, II. Schwefelmonoxid und Dischwefeldioxid als Komplexliganden

Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction

“… 31 , 34 , 35 Notably, complex 2 is only the third OSSO complex to be reported and only second to be structurally characterized. 29 , 36 – 38…”

“…For example, Schmid and co-workers reported that [(diphos) 2 Ir(η 2 -OSSO)][Cl] reacted with PPh 3 to form Ph 3 PO, Ph 3 PS, and [(diphos) 2 IrCl]. 36 Similarly, Rauchfuss and co-workers demonstrated that Cp 2 Nb(S 2 O)Cl reacted with Ph 3 P to form Cp 2 Nb(O)Cl and two equiv. of Ph 3 PS.…”

Activation of Elemental Sulfur at a Two‐Coordinate Platinum(0) Center

“…Monomeric side‐on MS 2 complexes of transition metals have been known for almost five decades [M=Nb, Ir, Rh] –. Oxidation of MS 2 complexes to give the corresponding oxidized complexes of the sulfur oxides S 2 O and S 2 O 2 are known –. However, Pt analogues are not reported until now.…”

Accurate Structure and Bonding Description of the Transition Metal‐Disulfur Monoxide Complexes [(PMe3)2M(S2O)] (M = Ni, Pd, Pt): Grimme Dispersion Corrected DFT Study

“…The known synthetic routes for the transition metal‐disulfur monoxide ( M –S 2 O) complexes are: (i) oxidation of disulfur ( M –S 2 ) complexes with oxygen atom transferring reagents, (ii) oxidation of disulfur ( M –S 2 ) complexes with dioxygen, (iii) reaction of imino‐oxo‐λ 4 ‐sulfane complexes with H 2 S, and (iv) reactions of solvated S 2 O(thf) x with metal complexes. The first example of the disulfur monoxide complex [(dppe)Ir(S 2 O)]Cl was reported by Schmid and co‐workers 7. The field has been expanded with well characterized examples of disulfur monoxide complexes of Nb,8 Mo,9–12 Re,13 Rh,7 Mn,13–16 Os,17 Ir,6,7,18 and Pt 19–21 .…”

“…The first example of the disulfur monoxide complex [(dppe)Ir(S 2 O)]Cl was reported by Schmid and co‐workers 7. The field has been expanded with well characterized examples of disulfur monoxide complexes of Nb,8 Mo,9–12 Re,13 Rh,7 Mn,13–16 Os,17 Ir,6,7,18 and Pt 19–21 . Ishii and co‐workers have reported the structure and properties of platinum‐S 2 O complex [(Ph 3 P) 2 Pt(S 2 O)] 21.…”