Die Kartoffel

Awe,

doi:10.1002/ardp.19512840209

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Enamin-weg1

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1981

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“…Unter dem Eindruck der Aweschen Arbeit [2] prüften wir, ob ein Enamin aus sek. Amin und Aldehyd das gesuchte Nucleophil ist (Enamine haben ähnlich gute nucleophile Eigenschaften wie Enolate [20] …”

Section: Enamin-wegunclassified

Struktur und Entstehung des farbigen Simon-Awe-Komplexes / Structure and Formation of the Coloured Simon-Awe Complex

Wiegrebe

Vilbig

1981

Zeitschrift Für Naturforschung B

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Abstract A nice blue colour arises from acetaldehyde, Na2[Fe(CN)5NO] • 2 H2O and piperidine (Simon-Awe Reaction). Structure elucidation of the blue material (leading to 1) by combustion analysis, ligand exchange to [Fe(CN)6]4-, reduction to β-aminoethanol and hydrolysis to glyoxal are described. - The blue complex does not contain the amine moiety but is formed via an enamine, an colourless immoniumsalt 2 and its hydrolysis to 1. - Loach's experiments are re-evaluated

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Section: Enamin-wegunclassified

Struktur und Entstehung des farbigen Simon-Awe-Komplexes / Structure and Formation of the Coloured Simon-Awe Complex

Wiegrebe

Vilbig

1981

Zeitschrift Für Naturforschung B

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Die Kartoffel

Cited by 1 publication

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Struktur und Entstehung des farbigen Simon-Awe-Komplexes / Structure and Formation of the Coloured Simon-Awe Complex

Struktur und Entstehung des farbigen Simon-Awe-Komplexes / Structure and Formation of the Coloured Simon-Awe Complex

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