Die Dampfdrucke von festem Chlor und festem Brom

Henglein, F. A.; Rosenberg, G. v.; Muchlinski, A.

doi:10.1007/bf01328395

Cited by 21 publications

(4 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…These results are quite surprising since the data of Giauque and Powell 28 exhibit a systematic offset of approximately +0.5%. However, except for the data of Henglein et al 37 and Harteck, 38 which differ significantly from the aforementioned three datasets, there were no other data available during that time. The measurements of Giauque and Powell 28 were derived from calorimetric experiments.…”

Section: Comparison Of the Equation Of State To Experimental Datamentioning

confidence: 95%

A fundamental equation of state for the calculation of thermodynamic properties of chlorine

2021

View full text Add to dashboard Cite

A fundamental equation of state is presented for the calculation of thermodynamic properties of chlorine. It is expressed in terms of the Helmholtz energy with the independent variables temperature and density. Based on the available experimental data from the literature, the equation is valid from the triple point temperature 172.17-440 K with a maximum pressure of 20 MPa. The quality of the equation is evaluated by comparisons with experimental measurements. Since the equation was developed in part for use in mixture models relevant for carbon capture and storage applications, special focus was also given to correct extrapolation behavior. K E Y W O R D S chlorine, equation of state, Helmholtz energy, thermodynamic properties 1 | INTRODUCTION Knowledge of thermodynamic properties is essential for many processes in chemical and process engineering as well as academic research. For industrial use, the properties have to be as accurate as possible and, additionally, easily accessible. In order to fulfill these requirements, equations of state are used. These equations are correlated to thermodynamic properties obtained with experiments carried out in laboratories. Therefore, the accuracy and range of validity of the equation of state is limited to the accessibility as well as the quality of the experimental data. The availability of thermodynamic properties is often quite limited for fluids that are dangerous to handle, for example, because they are toxic, flammable, or reactive with materials that are mounted in the apparatus. In this article, a new equation of state is presented for chlorine.Chlorine was discovered accidentally by Carl Wilhelm Scheele in 1774 by bleaching leaves and flowers. Its name was given by Humphry Davy in 1810 who realized that in fact chlorine is an element. In the following centuries, it became a very important substance in many different processes, for example, it is used in water purification, bleaching, medicines, paper production, and organic chemistry. At standard conditions, it is a greenish-yellow gas with a very strong smell. Because of its binding propensity, it is highly reactive with many substances. It is rarely found as an element in nature, but rather in combination with other substances, for example, sodium chloride. It is not flammable and only explosive

show abstract

Section: Comparison Of the Equation Of State To Experimental Datamentioning

confidence: 95%

A fundamental equation of state for the calculation of thermodynamic properties of chlorine

2021

View full text Add to dashboard Cite

show abstract

“…However, bromine does not interfere with the use of bromine trifluoride as a reagent in the analysis of alkali metal tungsten bronzes. Table 1 presents some useful physical data for compounds of the bromine-fluorine system (15,64,75,110,111,112 (69,128,129,130,134). If the temperature is kept below 40C°C, copper is recommended.…”

Section: A Properties Of Bromine Trifluoridementioning

confidence: 99%

Chemical Analysis of the Alkali Metal Tungsten Bronzes.

Raby¹,

Banks²

1964

Anal. Chem.

View full text Add to dashboard Cite

“…compared with 1.18 Bohr magnetons for UH3. 5 Although the data are not presented by Henry, the statement was made: "The absolute moment of uranium deuteride seems to be less, for all equal conditions of temperature and magnetic field, than that of the hydride." (1) Based on work performed under the auspices of the U. S. Atomic Energy Commission.…”

Section: Introductionmentioning

confidence: 99%

The Heat Capacity and Thermodynamic Functions of β-Uranium Deuteride from 5 to 350°K.^1,2

Abraham¹,

Osborne²,

Flotow³

et al. 1960

J. Am. Chem. Soc.

View full text Add to dashboard Cite

Die Dampfdrucke von festem Chlor und festem Brom

Cited by 21 publications

References 0 publications

A fundamental equation of state for the calculation of thermodynamic properties of chlorine

A fundamental equation of state for the calculation of thermodynamic properties of chlorine

Chemical Analysis of the Alkali Metal Tungsten Bronzes.

The Heat Capacity and Thermodynamic Functions of β-Uranium Deuteride from 5 to 350°K.^1,2

Contact Info

Product

Resources

About

Die Dampfdrucke von festem Chlor und festem Brom

Cited by 21 publications

References 0 publications

A fundamental equation of state for the calculation of thermodynamic properties of chlorine

A fundamental equation of state for the calculation of thermodynamic properties of chlorine

Chemical Analysis of the Alkali Metal Tungsten Bronzes.

The Heat Capacity and Thermodynamic Functions of β-Uranium Deuteride from 5 to 350°K.1,2

Contact Info

Product

Resources

About

The Heat Capacity and Thermodynamic Functions of β-Uranium Deuteride from 5 to 350°K.^1,2