Die Bedeutung der Strömungsverteilung für die Modellierung von chemischen Festbettreaktoren bei höheren Reynolds‐Zahlen und ausgedehnten Reaktionszonen
“…Carbonell [2] also used a two zone model for his analysis of the dispersion phenomena. In more recent work Vortmeyer et al [5,6] tried to use the complete radial void fraction profile, and so did Chang [3]. They followed the same itinerary outlined by Lerou and Froment [1] and Marivoet et al [21].…”
Section: Applicationmentioning
confidence: 92%
“…Carbonell [2] and Chang [3] used the structure of the bed to explain dispersion phenomena. Vortmeyer et al introduced the structural characteristics of the bed to improve their models for creeping flow in reactors [4] and for the theoretical prediction of fixed bed chemical reactor performance [5,6]. Cohen and Metzner [1] accounted for nonuniformities of the bed in the pressure drop relationship for both linear and non-Newtonian fluids.…”
“…Carbonell [2] also used a two zone model for his analysis of the dispersion phenomena. In more recent work Vortmeyer et al [5,6] tried to use the complete radial void fraction profile, and so did Chang [3]. They followed the same itinerary outlined by Lerou and Froment [1] and Marivoet et al [21].…”
Section: Applicationmentioning
confidence: 92%
“…Carbonell [2] and Chang [3] used the structure of the bed to explain dispersion phenomena. Vortmeyer et al introduced the structural characteristics of the bed to improve their models for creeping flow in reactors [4] and for the theoretical prediction of fixed bed chemical reactor performance [5,6]. Cohen and Metzner [1] accounted for nonuniformities of the bed in the pressure drop relationship for both linear and non-Newtonian fluids.…”
“…In small-diameter beds, packing heterogeneities near the wall lead to faster flow around the periphery of the bed. The effects of this bypass flow (also referred to as near-wall channeling) are mitigated by increasing radial dispersion 37 and pellet-to-bed diameter ratio 38 . Two approaches can be used when near-wall channeling effects play a significant role in the hydrodynamics.…”
Section: Axial Dispersion Is a Complex Function Of Flow Conditions Anmentioning
Fixed-bed adsorption is widely used in industrial gas separation and is the primary method for atmosphere revitalization in space. This paper analyzes the uncertainty of a one-dimensional, fixed-bed adsorption model due to uncertainty in several model inputs, namely, the linear-drivingforce (LDF) mass transfer coefficient, axial dispersion, heat transfer coefficients, and adsorbent properties. The input parameter uncertainties are determined from a comprehensive survey of experimental data in the literature. The model is first calibrated against experimental data from intra-bed centerline concentration measurements to find the LDF coefficient. We then use this LDF coefficient to extract axial dispersion coefficients from mixed, downstream concentration measurements for both a small-diameter bed (dominated by wall-channeling) and a large-diameter bed (dominated by pellet-driven dispersion). The predicted effluent concentration and temperature profiles are most strongly affected by uncertainty in LDF coefficient, adsorbent density, and void fraction. The uncertainty analysis further reveals that ignoring the effect of wall-channeling on apparent axial dispersion can cause significant error in the predicted breakthrough times of smalldiameter beds.
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