143 line emission cross-sections of Ca I and 15 line emission cross-sections of Ca II have been measured at an electron energy of 30eV. The optical excitation functions (OEF) are recorded in a range of electron energy from 0 to 200eV: 59 OEF for Ca I and 5 OEF for Ca II. The investigated lines are located in a spectrum region 227-745 nm. For the cross-sections of 5 singlet series and 10 triplet ones of Ca I, consideration has been given to series relationships that are characterized by the power relationship between the cross-section value and the principal quantum number of the upper level. Deviations from the power relationship take place in the perturbed Ca I series. The perturbations manifest themselves also by changing the OEF shape.