Dichlorofluoramine

Abstract

The standard disposal method for chlorine trifluorideThe chlorine involves the use of a soda lime tower.lJ

Reactions of dimethylaminodifluoroarsine. Coordination with boron acids and cleavage by hydrogen chloride

“…Mass spectrum (70 eV) [m/e (ion, relative intensity)]: 157 (C2H6-NAsF2+, 5), 156 (C2H5NAsF2+, 8), 138 (C2HfiNAsF+, 6), 113 (AsF2+, 8), 94 (AsF+, 3), 81 (?, 7), 58 (?, 3), 47 (SiF+, 3), 45 (C2H6NH+, 45), 44 (C2H6N+, 100), 43 (C2H5N+, 46), 42 (C2H4N+, 79), 41 (C2H3N+, 18), 40 (C2H2N+, 10), 39 (C,HN+, 9), 38 (C2N+, 3), 30 (CH3NH+, 13), 29 (CH3N+, 19), 28 (CH2N+, N3+, 90), 27 (CHN+,25), 26 (CN+, 3), 15 (CH3+, 43), 14 (N+,CH3+,8). No other peaks of relative intensity greater than 2 were observed except a strong H30+ peak at 18.…”

N‐Fluorosulfonyldichloroamine1

“…According to IR, NMR, and mass spectra the isomeric form ClS0,NClF is less probable. Compound (1) liberates iodine from aqueous potassium iodide solution, the first step of the hydrolysis being formation of hypochlorous acid : FSO,NCl, + HOH ---t FS0,NClH + HOCl (2) N-Fluorosulfonylmonochloroamine (2) could be isolated in the form of its amide by treatment with tetraphenylphosphonium or tetraphenylarsonium chloride : FS0,NSO (0.1 mole) is placed in a 100ml two-necked quartz flask fitted with a delivery tube, refluxing condenser, and T-piece for purging with dry nitrogen. ClF (0.25 mole) is fed into the flask, the internal temperature of which is not allowed to increase beyond 30°C.…”

Redistribution and Exchange Reactions in Groups IIB-VIIB

“…Although mixed chlorofluorides of nitrogen (154,188) and mixed chlorobromo complex ions of bismuth (146) are known, the equilibria between mixed and end compounds have not been investigated. For phosphorus NF2C1 + NFC12 NF3 + NCI, and arsenic halides, the equilibria of Eq.…”