Dichloro(η<sup>5</sup>-cyclopentadienyl)(phenylimido)vanadium(V)

Chan, M. C. W.; Cole, Jacqueline M.; Gibson, Vernon C.; Howard, J. A. K.

doi:10.1107/s0108270196012875

Cited by 5 publications

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“…The existence of both inter- and intramolecular hydrogen bonding of C−H donor units where chlorine acts as the acceptor atom has been reported previously. , It is difficult to compare this bonding situation with vanadocene monochlorides due to the few examples of such compounds. But, comparisons can be made with vanadocene dichlorides containing monoalkylated cyclopentadienyl ligands that have the substituents directly above and below the chlorine atoms when the alkyl group is Pr i (cf .…”

Section: Resultsmentioning

confidence: 79%

Synthesis and Structure of Amino-Functionalized Cyclopentadienyl Vanadium Complexes and Evaluation of Their Butadiene Polymerization Behavior

et al. 2002

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We have synthesized a number of bis-1,1,-amino-functionalized vanadocenes and vanadocene monochlorides; the bis-1,1,-amino-functionalized vanadocenes represent the first examples of structurally characterized compounds of this type, and the bis-1,1,-aminofunctionalized vanadocene monochlorides represent the first examples synthesized and characterized. We report the catalytic behavior of some of the complexes toward butadiene and observe that amino-functionalized cyclopentadienyl vanadium phosphine chloride complexes behave much differently from their nonfunctionalized cyclopentadienyl derivatives.

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Section: Resultsmentioning

confidence: 79%