“…Phonon engineering, i.e., targeted modification of phonon modes in nanostructures to enhance their thermal [5,9,10], electrical [9] and optical properties [11,12], manifests itself as a powerful tool for the optimization of nanoscale thermal transport [5,9,10]. Nanomaterials with high thermal conductivity (TC), such as graphene, are promising candidates as heat spreaders and interconnectors [13][14][15][16], while nanomaterials with low thermal conductivity and high electrical conductivity can be used for thermoelectric applications. The efficiency of the thermoelectric energy conversion, figure of merit ZT, is directly proportional to the electrical conductivity and inversely proportional to the total thermal conductivity: ZT = S 2 σT/ κ ph + κ el , where S is the Seebeck coefficient, σ is the electrical conductivity, T is the absolute temperature, and κ ph and κ el are the phonon and electron thermal conductivities, respectively.…”