The
ability to actuate liquids remains a fundamental challenge
in smart microsystems, such as those for soft robotics, where devices
often need to conform to either natural or three-dimensional solid
shapes, in various orientations. Here, we propose a hierarchical nanotexturing
of piezoelectric films as active microfluidic actuators, exploiting
a unique combination of both topographical and chemical properties
on flexible surfaces, while also introducing design concepts of shear
hydrophobicity and tensile hydrophilicity. In doing so, we create
nanostructured surfaces that are, at the same time, both slippery
(low in-plane pinning) and sticky (high normal-to-plane liquid adhesion).
By enabling fluid transportation on such arbitrarily shaped surfaces,
we demonstrate efficient fluid motions on inclined, vertical, inverted,
or even flexible geometries in three dimensions. Such surfaces can
also be deformed and then reformed into their original shapes, thereby
paving the way for advanced microfluidic applications.