Abstract:Dimethyldichlorosilane is one of the most widely used monomers in the organic silicon industry chain. In the preparation process, it can be obtained by exchanging functional groups through disproportionation reaction. In this research, the disproportionation mechanism catalyzed by ZSM-5(4T)@MIL-53(Al) and AlCl3/ZSM-5(4T)@MIL-53(Al) core-shell catalysts was studied by using the density functional theory on the level of M06-2X/Def2-TZVP. The results showed that the two catalysts possessed different catalytic eff… Show more
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