To indicate that atomic weights of
many elements are not constants
of nature, in 2009 and 2011 the Commission on Isotopic Abundances
and Atomic Weights (CIAAW) of the International Union of Pure and
Applied Chemistry (IUPAC) replaced single-value standard atomic weight
values with atomic weight intervals for 12 elements (hydrogen, lithium,
boron, carbon, nitrogen, oxygen, magnesium, silicon, sulfur, chlorine,
bromine, and thallium); for example, the standard atomic weight of
nitrogen became the interval [14.00643, 14.00728]. CIAAW recognized
that some users of atomic weight data only need representative values
for these 12 elements, such as for trade and commerce. For this purpose,
CIAAW provided conventional atomic weight values, such as 14.007 for
nitrogen, and these values can serve in education when a single representative
value is needed, such as for molecular weight calculations. Because
atomic weight values abridged to four figures are preferred by many
educational users and are no longer provided by CIAAW as of 2015, we provide a table containing both standard atomic
weight values and conventional atomic weight values abridged to four
figures for the chemical elements. A retrospective review of changes
in four-digit atomic weights since 1961 indicates that changes in
these values are due to more accurate measurements over time or to
the recognition of the impact of natural isotopic fractionation in
normal terrestrial materials upon atomic weight values of many elements.
Use of the unit “u” (unified atomic mass unit on the
carbon mass scale) with atomic weight is incorrect because the quantity
atomic weight is dimensionless, and the unit “amu” (atomic
mass unit on the oxygen scale) is an obsolete term: Both should be
avoided.