The Effluent Monitoring Program characterizes and monitors liquid waste streams from 300 Area buildings owned by the U.S. Department of Energy and managed by the Pacific Northwest labor at or^.'^' This program is managed by the Pacific Northwest Laboratory. This report summarizes the results of characterizing and monitoring the following sources during calendar year 1994 (the first year of the program): liquid waste streams from Buildings 306, 320, 324, 326, 331, and 3720; treated and untreated Columbia River water (influent); and water at the confluence of the waste streams (that is, end-of-pipe). Data were collected from March to December before the sampling system installation was completed. Data from this initial part of the program are considered tentative.Concentrations and clearance times at end-of-pipe were highly dependent on waste stream flow rates, dispersion, and the mechanical action of sumps. When present, the sumps had the greatest impact on clearance times. In the absence of sump activity, dispersion and flow rate were the controlling factors.Initial evaluations of field transportable gas chromatography/mass spectrometry, adsorptive stripping voltametry, solid phase extraction, and continuous monitoring of flow, pH, and conductivity were favorable. These technologies illustrated the highly variable nature of the effluent streams and the potential to improve current characterization practices.