An
off-resonance broadband photoacoustic spectroscopy (PAS) technique
with a supercontinuum laser (SCL) in the near-infrared range is demonstrated
for biogas measurements with different biomass matrices. The PAS sensor
system has been calibrated with known concentrations of methane (CH4), carbon dioxide (CO2), water vapor (H2O vapor), and hydrogen sulfide (H2S). A laboratory-scale
bioreactor was set up to monitor CH4 and CO2 generation using the SCL-PA sensor system. The obtained results
show the suitability of the PAS sensor to be employed in a fully operational
large scale biogas plant for online monitoring. The periodic variations
in concentration for CH4, CO2, and H2O vapor were monitored in a large scale cattle dung based biogas
plant in real-time, and the operating ranges were measured to be around
50–65%, 34–48%, and 0–1%, respectively. The SCL-PA
sensor was also employed at two different Sewage Treatment Plants
in Chennai, Tamilnadu, India, where along with CH4 (60–63%),
CO2 (34–38%), and H2O vapor (0.8–1%),
trace concentration levels of H2S were found to be around
0.04–1%.