As seismic events continue to pose significant threats to urban infrastructure, leveraging smartphones equipped with accelerometers for real-time monitoring has gained prominence. To ascertain the reliability and sensitivity of smartphone-based measurements, an in-depth characterization of their response is essential. This article presents a thorough characterization of the performance of typical accelerometers installed on three distinct smartphone models. For this, a novel experimental apparatus has been developed to conduct a comparative study involving three different smartphones against a reference accelerometer, determining the accelerometer’s transfer functions red for Fourier frequencies 0.1 - 40 Hz, demonstrating a higher sensitivity than expected. Possible ways and solutions to the implementation in future distributed networks of heterogeneous and synchronized sensors, capable of independently generating and validating timely alerts in particular seismic events, are also discussed.