“…With the rapid growth of industrialization progress, energy crisis and environmental problems have become extremely serious, which is stimulating the development of advanced materials. In recent years, vanadates have attracted lots of attention due to their unusual electrochemical, redox properties, and potential applications as sodium‐ion batteries, photoanodes, supercapacitors, gas sensors, and so on . Especially, iron vanadates FeVO 4 , Fe 2 V 4 O 13 , FeV 2 O 4 , and FeV 3 O 8 semiconductors exhibit narrow bandgap, high chemical stability, eco‐friendly, and low‐cost, which make them become promising photoelectrode materials for solar photoelectrochemical water splitting, lithium‐ion batteries, and Fenton‐like catalysts for degradation of organic pollutant .…”