Development of pyrolysis–GC with selective detection: coupling of pyrolysis–GC to atomic emission detection (py–GC–AED)

Ross, A.B.; Junyapoon, Suwannee; Bartle, Keith D.; Jones, James C. Peyton; Williams, Alan

doi:10.1016/s0165-2370(00)00179-0

Cited by 11 publications

(1 citation statement)

References 8 publications

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“…Therefore, GC coupled to an atomic emission detector (GC-AED or GC × GC-AED) is a viable option ( Lorentz et al, 2017 ). An AED is a multi-element detector technique which, coupled to a GC, has the widest element range of all detectors (up to 23 elements including halogens and metals such as Fe, Pb, Ni and Si) ( Ross et al, 2001 , Tranchida and Mondello, 2019 ). The GC (× GC)-effluent is directed into a He plasma chamber where all elements are atomized and excited.…”

Section: State-of-the-art Molecular Characterization Techniquesmentioning

confidence: 99%

Opportunities and challenges for the application of post-consumer plastic waste pyrolysis oils as steam cracker feedstocks: To decontaminate or not to decontaminate?

et al. 2022

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Section: State-of-the-art Molecular Characterization Techniquesmentioning

confidence: 99%

Opportunities and challenges for the application of post-consumer plastic waste pyrolysis oils as steam cracker feedstocks: To decontaminate or not to decontaminate?

et al. 2022

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Microwave Plasma Systems in Optical and Mass Spectroscopy

Jankowski

Reszke²,

Broekaert

et al. 2011

Encyclopedia of Analytical Chemistry

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The art and science of microwave plasma (MWP) optical and mass spectroscopy is briefly presented including very recent advances in the field up to 2011. The use of MWPs as radiation sources for optical emission spectroscopy (OES) and atomic fluorescence spectroscopy (AFS) and as atom reservoirs for atomic absorption spectroscopy (AAS), cavity ringdown spectroscopy (CRDS), and laser‐enhanced ionization spectroscopy (LEIS) as well as ion sources for mass spectrometry (MS) is treated. Devices for producing both E‐type capacitively coupled microwave plasma (CMP)‐electrode and microwave‐induced plasma (MIP)‐electrodeless MWPs, including inductively coupled plasma (ICP)‐like H‐type plasmas, are classified and discussed, in addition to methods of their diagnostics, and results for the analytically relevant plasma parameters are presented. The means of generation of symmetrical plasmas and uses of microplasma devices are also presented with an effort to comment on general classification of microwave (MW) cavities. Further, the use of MWs for boosting of glow discharges (GDs) is treated along with other tandem sources. Methods for the introduction of gaseous, liquid, and solid samples into the MWP are discussed. They include direct vapor sampling (DVS), chemical vapor generation (CVG), and hydride generation (HG) techniques; dry aerosol generation techniques (electrothermal vaporization (ETV); spark ablation (SA); laser ablation (LA); and continuous powder introduction (CPI) as well as wet aerosol generation techniques using both solution and slurry nebulization. Special reference is made to coupling with gas chromatography (GC) and also with various separation techniques for liquids including high‐performance liquid chromatography (HPLC). The analytical figures of merit in the case of OES with low‐power and high‐power MIP, CMP, microwave plasma torch (MPT), MWP‐electrode sources including rotating field sustained plasma and H‐type MWP as well as microplasmas are given. There are also described cases of atomic absorption, fluorescence, and laser ionization with these sources. The developments in MS in the case of both low‐power and high‐power MWPs and in the case of various types of sample introduction techniques are discussed. Applications of MWP analytical spectroscopy are in the fields of biological samples with special reference to microanalysis, and of environmental and industrial samples with special emphasis on element speciation, on‐line monitoring, particle sizing, and direct solids analysis. A critical comparison of the methodology with other spectroscopic methods for the determination of the elements and their species is given.

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Microwave Plasma Systems in Optical and Mass Spectroscopy

Jankowski

Reszke²,

Broekaert

2016

Encyclopedia of Analytical Chemistry

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The art and science of microwave plasma (MWP) optical and mass spectroscopy is briefly presented including very recent advances in the field up to 2015. The use of MWPs as radiation sources for optical emission (OES) and atomic fluorescence (AFS) spectroscopy and as atom reservoirs for atomic absorption (AAS) and cavity ringdown (CRDS) spectroscopy as well as ion sources for both elemental and molecular mass spectrometry (MS) is treated. Devices for producing both E‐type capacitively coupled microwave plasma (CMP)‐electrode and microwave‐induced plasma (MIP)‐electrodeless MWPs, including ICP‐like H‐type plasmas, are classified and discussed, in addition to techniques of their diagnostics, and results for the analytically relevant plasma parameters are presented. The means of generation of voluminous symmetrical plasmas and uses of microplasma devices are also presented with an effort to comment on general classification of microwave cavities. Further, the use of microwaves for boosting of glow discharges (GDs) and laser‐induced plasmas (LIBS) is treated along with other tandem sources. Methods for introduction of gaseous, liquid, and solid samples into the MWP are discussed. They include direct vapor sampling (DVS), chemical vapor generation (CVG) and hydride generation (HG) techniques, dry aerosol generation techniques (electrothermal vaporization (ETV), spark (SA) and laser ablation (LA) and continuous powder introduction (CPI)), and wet aerosol generation techniques using both solution and slurry nebulization. Special reference is made to coupling with gas chromatography (GC) and also with various separation techniques for liquids including high‐performance liquid chromatography (HPLC), supercritical fluid chromatography (SFC), and size‐exclusion chromatography (SEC). The analytical figures of merit in the case of OES with MIPs, CMPs, microwave plasma torch (MPT), MWP‐electrode sources including rotating‐field‐sustained plasma, and H‐type MWP as well as microplasmas are given. There are also described cases of atomic absorption and fluorescence with these sources. The developments in both elemental and molecular MS in the case of both cold and hot MWPs and in the case of various types of sample introduction techniques are discussed. Applications of MWP analytical spectroscopy are in the fields of biological, clinical, environmental, and industrial samples with special reference to multielement analysis, element speciation, on‐line monitoring, particle sizing, and direct solids analysis. A critical comparison of the methodology with other spectroscopic methods for the determination of the elements and their species is given.

show abstract

Development of pyrolysis–GC with selective detection: coupling of pyrolysis–GC to atomic emission detection (py–GC–AED)

Cited by 11 publications

References 8 publications

Opportunities and challenges for the application of post-consumer plastic waste pyrolysis oils as steam cracker feedstocks: To decontaminate or not to decontaminate?

Opportunities and challenges for the application of post-consumer plastic waste pyrolysis oils as steam cracker feedstocks: To decontaminate or not to decontaminate?

Microwave Plasma Systems in Optical and Mass Spectroscopy

Microwave Plasma Systems in Optical and Mass Spectroscopy

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