Development of Polypropylene-based Thermoplastic Elastomers with Crumb Rubber by Dynamic Vulcanization: A Potential Route for Rubber Recycling

Abstract

In our current paper the preparation and properties of thermoplastic elastomer produced by dynamic vulcanization is presented and discussed. We dynamically vulcanized natural and styrene butadiene rubber (NR/SBR) phase by continuous extrusion. Dispersion and in-situ vulcanization of the rubber phase occurred simultaneously in a co-rotating twin screw extruder. We used a random polypropylene copolymer (rPP) as the thermoplastic matrix and untreated crumb rubber (CR) to partially substitute the neat fresh rubber in order to check whether this is a potential recycling route for waste rubber products. We studied the effect of various rubber formulations, various processing conditions (screw speed and configuration) and various CR particle size distributions by characterizing the mechanical performance of the thermoplastic dynamic vulcanizates (TDVs) with tensile and hardness tests and their morphology by evaluating SEM micrographs taken from the fracture surfaces of the tensile specimens. The results showed that increasing screw speed and more high-shear elements in the screw setup led to a finer dispersion of the rubber phase, resulting in improved mechanical properties. The ultimate tensile properties of the best TDVs reached 20.5 MPa in tensile strength and 550 % in strain at break. However, partial replacement of the fresh rubber with untreated CR caused a significant deterioration in mechanical properties, due to poor adhesion between the CR particles and the matrix and rubber. This suggests that some kind of pre-treatment (e.g. by microwave or other devulcanization techniques) is necessary to enhance the surface activity of the CR particles.

Investigation of mechanical properties and microstructural analysis of polymeric waste strengthened hybrid composites

“…Istvan Zoltan Halasz et al 12 investigated the SBR/NR (70/30) blended with pyrolytic Carbon Black (pCB (60 phr)), CB (60 phr), and CB/Naphthenic Oil (Noil) (60/30). The incorporation of CB/Noil in SBR/NR composites improved the E b while diminishing the hardness.…”

Do descarte ao reaproveitamento do resíduo de estireno-butadieno (SBRr): produção de compostos de PA6/SBRr compatibilizados com SEBS-MA e reforçados com argila montmorilonita

“…Os materiais poliméricos têm merecido atenção especial neste cenário, uma vez que os resíduos pós-consumo e pós-industrial têm aumentado em quantidades excessivas nos ecossistemas naturais (Formela et al, 2019;Camargo & Saron, 2020;. Nesse contexto, os resíduos elastoméricos vulcanizados, os quais são amplamente empregados em grandes quantidades na indústria de transformação apresentam-se como os grandes vilões (Halász et al, 2020;Fazli & Rodrigue, 2020). O impacto ambiental ocasionado pelo descarte inadequado tem mobilizado setores da sociedade, visando soluções para o correto tratamento e destinação destes materiais vulcanizados (Luna et al, 2020;Datta et al, 2023).…”

Hybrid reinforcement of styrene‐butadiene rubber nanocomposites with carbon black, silica, and graphene

“…The two most common synthetic rubbers in tyres are butadiene rubber (BR) and styrene‐butadiene rubber (SBR). Their global production rates are around 3.4 and 5.3 million tons/year, respectively 4,5 …”