Development of novel transition metal-catalyzed synthetic approaches for the synthesis of a dihydrobenzofuran nucleus: a review
Rabia Ashraf,
Ameer Fawad Zahoor,
Kulsoom Ghulam Ali
et al.
Abstract:The dihydrobenzofuran scaffolds demonstrate a wide range of biological activities. Several transition metals have been employed as catalysts for the efficacious synthesis of these structurally important frameworks.
“… 13 Fe catalysts are favorable because they are less harmful and easily available. Nowadays, efficient transformations can be carried out with high enantioselectivities by using chiral metal complexes 14–16 (transition metals 17 i.e. , Co, 18 Zr, 19–21 Pt, 12,22 Hf 23 or Cu 24 and non-transition metals i.e.…”
Baeyer–Villiger oxidation is a renowned reaction that provides an efficient route for the synthesis of biologically active natural products such as alkaloids, terpenoids, polyketides and fatty acid-based naturally occurring organic compounds.
“… 13 Fe catalysts are favorable because they are less harmful and easily available. Nowadays, efficient transformations can be carried out with high enantioselectivities by using chiral metal complexes 14–16 (transition metals 17 i.e. , Co, 18 Zr, 19–21 Pt, 12,22 Hf 23 or Cu 24 and non-transition metals i.e.…”
Baeyer–Villiger oxidation is a renowned reaction that provides an efficient route for the synthesis of biologically active natural products such as alkaloids, terpenoids, polyketides and fatty acid-based naturally occurring organic compounds.
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